CREATE USERuser[IDENTIFIED BY [PASSWORD] 'password'] [,user[IDENTIFIED BY [PASSWORD] 'password']] ...
The CREATE USER statement was
added in MySQL 5.0.2. This statement creates new MySQL accounts.
To use it, you must have the global CREATE
USER privilege or the
INSERT privilege for the
mysql database. For each account,
CREATE USER creates a new record
in the mysql.user table that has no
privileges. An error occurs if the account already exists. Each
account is named using the same format as for the
GRANT statement; for example,
'jeffrey'@'localhost'. If you specify only
the user name part of the account name, a host name part of
'%' is used. For additional information about
specifying account names, see Section 12.4.1.3, “GRANT Syntax”.
The account can be given a password with the optional
IDENTIFIED BY clause. The
user value and the password are given
the same way as for the GRANT
statement. In particular, to specify the password in plain text,
omit the PASSWORD keyword. To specify the
password as the hashed value as returned by the
PASSWORD() function, include the
PASSWORD keyword. See
Section 12.4.1.3, “GRANT Syntax”.
This statement may be recorded in a history file such as
~/.mysql_history, which means that
plaintext passwords may be read by anyone having read access
to such files.

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